dielectric
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dielectric


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A dielectric is an electrical insulator that can be polarized by an applied electric field. When a dielectric is placed in an electric field, electric charges do not flow through the material, as in a conductor, but only slightly shift from their average equilibrium positions causing dielectric polarization. Because of dielectric polarization, positive charges are displaced toward the field and negative charges shift in the opposite direction. This creates an internal electric field which reduces the overall field within the dielectric itself.[1] If a dielectric is composed of weakly bonded molecules, those molecules not only become polarized, but also reorient so that their symmetry axis aligns to the field.[1]
Although the term "insulator" implies low electrical conduction, "dielectric" is typically used to describe materials with a high polarizability. The latter is expressed by a number called the dielectric constant. A common, yet notable example of a dielectric is the electrically insulating material between the metallic plates of a capacitor. The polarization of the dielectric by the applied electric field increases the capacitor's surface charge.[1]

Dielectric dispersion

In physics, dielectric dispersion is the dependence of the permittivity of a dielectric material on the frequency of an applied electric field. Because there is always a lag between changes in polarization and changes in an electric field, the permittivity of the dielectric is a complicated, complex-valued function of frequency of the electric field. It is very important for the application of dielectric materials and the analysis of polarization systems.
This is one instance of a general phenomenon known as material dispersion: a frequency-dependent response of a medium for wave propagation.

When the frequency becomes higher:

1. it becomes impossible for dipolar polarization to follow the electric field in the microwave region around 1010 Hz;
2. in the infrared or far-infrared region around 1013 Hz, ionic polarization and molecular distortion polarization lose the response to the electric field;
3. electronic polarization loses its response in the ultraviolet region around 1015 Hz.
In the frequency region above ultraviolet, permittivity approaches the constant ε0 in every substance, where ε0 is the permittivity of the free space. Because permittivity indicates the strength of the relation between an electric field and polarization, if a polarization process loses its response, permittivity decreases.

Dielectric relaxation

Dielectric relaxation is the momentary delay (or lag) in the dielectric constant of a material. This is usually caused by the delay in molecular polarization[disambiguation needed ] with respect to a changing electric field in a dielectric medium (e.g. inside capacitors or between two large conducting surfaces). Dielectric relaxation in changing electric fields could be considered analogous to hysteresis in changing magnetic fields (for inductors or transformers). Relaxation in general is a delay or lag in the response of a linear system, and therefore dielectric relaxation is measured relative to the expected linear steady state (equilibrium) dielectric values. The time lag between electrical field and polarization implies an irreversible degradation of free energy(G).
In physics, dielectric relaxation refers to the relaxation response of a dielectric medium to an external electric field of microwave frequencies. This relaxation is often described in terms of permittivity as a function of frequency, which can, for ideal systems, be described by the Debye equation. On the other hand, the distortion related to ionic and electronic polarization shows behavior of the resonance oroscillator type. The character of the distortion process depends on the structure, composition, and surroundings of the sample.
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